On January 15, 2010, McConville, Matthew; Blacker, John; Xiao, Jianliang published an article.Application In Synthesis of 2-Methyl-2-propylpropane-1,3-diol The title of the article was Heck reaction in diols and cascade formation of cyclic ketals. And the article contained the following:
The regioselective Heck arylation of BuOCH:CH2 in alcs. was utilized for the formation of a variety of cyclic ketals. When carried out in ethylene glycol, propane-1,2-diol, or propane-1,3-diol, the Pd-catalyzed arylation afforded dioxolanes or dioxanes directly. With diols such as glycerol, 3-chloropropane-1,2-diol, and 2-methylpropane-1,3-diol, isolation of the Heck adducts and the use of an acid catalyst for the ketalization were necessary; an efficient phosphate was identified. The procedure provides a new pathway for the synthesis of cyclic ketals, particularly those that are functionalized. The experimental process involved the reaction of 2-Methyl-2-propylpropane-1,3-diol(cas: 78-26-2).Application In Synthesis of 2-Methyl-2-propylpropane-1,3-diol
The Article related to bu vinyl ether aryl bromide diol regioselective heck ketalization, enol ether diol ketalization phosphate catalyst, cyclic ketal green preparation, dioxolane green preparation, dioxane green preparation and other aspects.Application In Synthesis of 2-Methyl-2-propylpropane-1,3-diol
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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts