On April 30, 2000, Femia, Frank J.; Babich, John W.; Zubieta, Jon published an article.Reference of 2,2′-(tert-Butylazanediyl)diethanol The title of the article was Structural systematics of the {ReO}3+ core with ‘3+2’ ligand donor sets. And the article contained the following:
The reactions of [ReOCl3(PPh3)2] with the appropriate tridentate and bidentate ligands provide a facile route for the synthesis of a diverse family of compounds of the {Re(V)O}3+ core with a ‘3+2′ ligand set. The structural prototype for the series is [ReO{OCH2CH2SCH2CH2O}{OCH2CH2SCH2CH2OH}] (1) which exhibits distorted octahedral geometry, defined by the two oxygen and sulfur donors of the tridentate ligand in a facial arrangement, the oxygen and sulfur donors of the bidentate ligand, and the oxo-donor. Compounds 2-5 are variants [ReO(OCH2CH2SCH2CH2O)(S and N)] where S and N is a bidentate ligand of the mercaptopyridine or mercaptopyrimidine class. Similarly, compounds 6-17 are [ReO(OCH2CH2NRCH2CH2O)(S and N)] with the same bidentate ligands as for 2-5 and R = Me, Et, Bu, and t-Bu. The experimental process involved the reaction of 2,2’-(tert-Butylazanediyl)diethanol(cas: 2160-93-2).Reference of 2,2′-(tert-Butylazanediyl)diethanol
The Article related to rhenium oxo thiobisethanolato iminobisethanolato mercaptopyridine mercaptopyrimidine preparation, thioether rhenium oxo mercaptopyridine mercaptopyrimidine preparation, crystal structure rhenium oxo thiobisethanolato iminobisethanolato mercaptopyridine mercaptopyrimidine and other aspects.Reference of 2,2′-(tert-Butylazanediyl)diethanol
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