On April 16, 2021, Sunagawa, Denise E.; Ishida, Naoyoshi; Iwamoto, Hiroaki; Ohashi, Masato; Fruit, Corinne; Ogoshi, Sensuke published an article.HPLC of Formula: 143-10-2 The title of the article was Synthesis of Fluoroalkyl Sulfides via Additive-Free Hydrothiolation and Sequential Functionalization Reactions. And the article contained the following:
A modular synthetic method, involving a hydrothiolation, silylation, and fluoroalkylation, for the construction of highly functionalized fluoroalkyl sulfides has been developed. The use of the aprotic polar solvent N,N-dimethylacetamide enables the additive-free chemoselective hydrothiolation of tetrafluoroethylene, trifluorochloroethylene, and hexafluoropropene with various thiols. Stepwise functionalization of the tetrafluoroethyl ethers and a chlorotrifluoroethyl ether by silylation with TMSCl and LDA followed by reactions with aryl iodides, a chloroalkene, or acyl chlorides in the presence of CuOt-Bu and 1,10-phenanthroline convert the hydrothiolated intermediates into the tetrafluoroethyl sulfides in high efficiency. The method avoids the use of the environmental pollutant Halon-2402 (1,2-dibromo-1,1,2,2-tetrafluoroethane), which was employed as a building block in a reported synthetic route. Tetrafluoroethylene is a potential carcinogen and should be used in a well-ventilated fume hood. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).HPLC of Formula: 143-10-2
The Article related to tetrafluoroethyl silyltetrafluoroethyl thioether chemoselective preparation, dimethylacetamide solvent hydrothiolation tetrafluoroethylene chlorotrifluoroethylene hexafluoropropene thiol, fluoroalkyl thioether modular preparation, base mediated silylation hydrofluoroalkyl thioether chlorotrimethylsilane and other aspects.HPLC of Formula: 143-10-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts