In 2019,Journal of Catalysis included an article by Thiruvengetam, Prabaharan; Chakravarthy, Rajan Deepan; Chand, Dillip Kumar. Application of 100-55-0. The article was titled 《A molybdenum based metallomicellar catalyst for controlled and chemoselective oxidation of activated alcohols in aqueous medium》. The information in the text is summarized as follows:
A surfactant based oxodiperoxo molybdenum complex, which could activate mol. oxygen, has been employed as a catalyst for controlled oxidation of benzylic alcs. to corresponding carbonyls I (R = 4-OMe, 3-Br, 4-NMe2, etc.) and II (R = 4-NO2, 4-SMe, 4-allyloxy, etc.; R’ = Me, Et, Ph, etc.). The oxidation reactions were carried out under aqueous environment, however, in the absence of any extraneous base or co-catalyst. Sensitive/oxidizable functional groups like cyano, sulfide, hydroxyl, aryl-hydroxyl, alkene (internal/terminal), alkyne (internal/terminal), and acetal were tolerated during the transformations. Such selectivity is attributed to the mild nature of the catalyst. The methodol. could also be scaled-up for multi-gram synthesis and the protocol is likely to find practical use since it requires an inexpensive recyclable-catalyst and easily available oxidant (under green conditions). A plausible mechanism is proposed with the help of preliminary computational study. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Application of 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Application of 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts