Name: 2,6-PyridinedimethanolIn 2021 ,《Synthetic platform for mono-functionalised tridentate macrocycles as key precursors of mechanically-linked macromolecular systems》 appeared in Organic Chemistry Frontiers. The author of the article were Sharma, Atul Kumar; Malineni, Jagadeesh; Box, Simon; Ghiassinejad, Sina; van Ruymbeke, Evelyne; Fustin, Charles-Andre. The article conveys some information:
We report here a synthetic platform toward mono-functionalized tridentate macrocycles based on a pyridine-2,6-bis-carboxamide motif. These macrocycles bear a variety of functional groups at the fourth position of the pyridine, giving access to a wide range of synthetic methods for further derivatization or preparation of more complex structures such as mech. interlocked mols. or polymer materials. To illustrate the potential of this family of macrocycles a series of square planar palladium complex-based pseudorotaxanes, containing different axles and functional groups on the ring, are synthesized, and then used to prepare a macro-pseudorotaxane, i.e. a polymer containing a rotaxane junction, and mech.-linked gels by a one-pot and a polyrotaxane approach. The experimental part of the paper was very detailed, including the reaction process of 2,6-Pyridinedimethanol(cas: 1195-59-1Name: 2,6-Pyridinedimethanol)
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Name: 2,6-Pyridinedimethanol
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