《Mn(IV), Co(II) and Ni(II) complexes of the Schiff bases of 2-hydroxy-naphthaldehyde with amino alcohols: synthesis, characterization and electrochemical study; DFT study and Catecholase activity of Mn(IV) complex》 was written by Sagar, Shipra; Parween, Arfa; Mandal, Tarun K.; Lewis, William; Naskar, Subhendu. Recommanded Product: 3-Aminopropan-1-ol And the article was included in Journal of Coordination Chemistry in 2020. The article conveys some information:
Four new mononuclear complexes, [MnIV(L1)2] (1), [CoII(HL1)2] (2), [NiII(HL1)2] (3), and [NiII(HL2)2] (4), with ligands H2L1 = (2-hydroxyethylimino)methylnaphthol and H2L2 = (3-hydroxypropylimino)methylnaphthol have been synthesized, characterized, and their catecholase activities have been studied. Single-crystal x-ray diffraction study shows that 1 crystallizes in P43212 space group and adopts an octahedral geometry in meridional fashion, whereas 4 with a square planar geometry crystallizes in P21/n space group. The catecholase activity has been investigated in acetonitrile by UV-Vis spectrophotometric technique. The kinetic study revealed that 1 has a moderate catecholase activity (kcat = 812 h-1), whereas 2-4 are inactive. Electronic structure of 1 and 4 has been established by theor. calculation Structures of both complexes have been optimized by DFT. Exptl. electronic spectra of the complexes have been corroborated by TD-DFT anal. In the experimental materials used by the author, we found 3-Aminopropan-1-ol(cas: 156-87-6Recommanded Product: 3-Aminopropan-1-ol)
3-Aminopropan-1-ol(cas: 156-87-6) belongs to anime. Large quantities of aliphatic amines are made synthetically. The most widely used industrial method is the reaction of alcohols with ammonia at a high temperature, catalyzed by metals or metal oxide catalysts (e.g., nickel or copper). Mixtures of primary, secondary, and tertiary amines are thereby produced.Recommanded Product: 3-Aminopropan-1-ol
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