Nisanci, Bilal; Dagalan, Ziya published the artcile< A facile and highly efficient transfer hydrogenation of ketones and aldehydes catalyzed by palladium nanoparticles supported on mesoporous graphitic carbon nitride>, Formula: C8H9FO, the main research area is carbonyl compound ammonia borane palladium catalyst hydrogenation; alc preparation.
A novel transfer hydrogenation methodol. for the reduction of ketones (14 examples) and benzaldehyde derivatives (12 examples) to the corresponding alcs. using Pd nanoparticles supported on mesoporous graphitic carbon nitride (mpg-C3N4/Pd) as a reusable catalyst and ammonia borane as a safe hydrogen source in an aqueous solution MeOH/H2O (volume/volume = 1/1) was described. The catalytic hydrogenation reactions were conducted in a com. available high-pressure glass tube at room temperature and the corresponding alcs. were obtained in high yields in 2-5 min. Moreover, the presented transfer hydrogenation protocol showed partial halogen selectivity with bromo-, fluoro- and chloro-substituted carbonyl analogs. In addition, the present catalyst can be reused up to five times without losing its efficiency and scaling-up the reaction enabled α-methylbenzyl alc. to be produced in 90% isolated yield.
Journal of Chemical Research published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Formula: C8H9FO.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts