Ni, Hui-Qi; Li, Zi-Qi; Tran, Van T.; Engle, Keary M. published the artcile< Modular synthesis of non-conjugated N-(quinolin-8-yl) alkenyl amides via cross-metathesis>, Safety of But-3-en-1-ol, the main research area is amide terminal alkene olefin metathesis Grubbs catalyst directing group; internal alkene preparation; Alkene Functionalization; Alkenes; Directing group; Grubbs catalyst; Olefin metathesis.
We report a direct and modular method to access non-conjugated alkenyl amides containing the 8-aminoquinoline (AQ) directing auxiliary and related groups via cross-metathesis. In this way, readily available, AQ-containing, terminal β,γ-unsaturated amides can be coupled with various terminal alkenes to furnish internal alkene products that are otherwise difficult to prepare The value of this family of products stems from their ability to participate in a number of directed alkene functionalization reactions.
Tetrahedron published new progress about Alkenes Role: SPN (Synthetic Preparation), PREP (Preparation) (internal). 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, Safety of But-3-en-1-ol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts