《Effects of substituents on bridging ligands on the single-molecule magnet properties of Zn2Dy2 cluster complexes》 was written by Liu, Cai-Ming; Hao, Xiang; Zhang, De-Qing. Name: 2,6-PyridinedimethanolThis research focused onzinc dysprosium salen Schiff base pyridinedimethanol cluster complex preparation; magnetic property zinc dysprosium salen Schiff base pyridinedimethanol; crystal structure zinc dysprosium salen Schiff base pyridinedimethanol. The article conveys some information:
Two new Zn2Dy2 complexes were constructed from Zn (II) salen-type Schiff base complex fragment and 2,6-pyridinedimethanol (H2pdm) or its Br-substituted analog (4-bromopyridine-2,6-diyl)dimethanol (H2Brpdm); their mol. formulas are [Zn2Dy2(L)2(pdm)2(MeOH)2](ClO4)2 [1, H2L = N, N’- bis(3-methoxysalicylidene)-1,3-diaminopropane] and [Zn2Dy2(L)2(Brpdm)2(MeOH)2](ClO4)2 [2], the Dy (III) ions of which have a NO7 triangular dodecahedral coordination sphere. The two complexes show not only ferromagnetic interaction but also field-induced single-mol. magnet (SMM) behavior, which are rare Dy (III)-containing cluster complexes with the NO7 triangular dodecahedral coordination sphere that can show good magnetic relaxation. The energy barrier value of complex 2 is higher than those of complex 1 and the Dy (III) complexes with the DyNO7 triangular dodecahedral coordination configuration reported in the literature.2,6-Pyridinedimethanol(cas: 1195-59-1Name: 2,6-Pyridinedimethanol) was used in this study.
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. Pyridine-based materials are valued for their optical and physical properties as well as their medical potential. Additionally, pyridine-based natural products continue to be discovered and studied for their properties and to understand their biosynthesis.Name: 2,6-Pyridinedimethanol
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