Li, Xuan; Jiang, Min; Zhu, Xiaolong; Song, Xiuyan; Deng, Qirong; Lv, Jian; Yang, Daoshan published the artcile< A desulphurization strategy for Sonogashira couplings by visible light/copper catalysis>, Name: (4-Ethynylphenyl)methanol, the main research area is alkyne sulfonium salt desulfurization Sonogashira coupling copper catalyst.
Herein, a new copper-based catalyst, [(binap)(tpy)Cu]Cl I applied in the visible-light promoted Sonogashira coupling reactions has been developed. This mild protocol results in various substituted alkynes RCCH (R = Ph, 2-naphthyl, 2-thienyl, etc.) from simple sulfonium salts II (R1 = Ph, 1-naphthyl, 2H-1,3-benzodioxol-5-yl, etc.) which can be easily prepared from com. available and inexpensive substrates. This study will broaden the still limited strategies of copper photocatalysts in organic transformations.
Organic Chemistry Frontiers published new progress about Alkynes, aryl Role: RCT (Reactant), RACT (Reactant or Reagent). 10602-04-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C9H8O, Name: (4-Ethynylphenyl)methanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts