《Surface-Deactivated Core-Shell Metal-Organic Framework by Simple Ligand Exchange for Enhanced Size Discrimination in Aerobic Oxidation of Alcohols》 was written by Kim, Seongwoo; Lee, Jooyeon; Jeoung, Sungeun; Moon, Hoi Ri; Kim, Min. HPLC of Formula: 873-75-6 And the article was included in Chemistry – A European Journal in 2020. The article conveys some information:
Herein, through a simple post-synthetic ligand exchange (PSE) method, surface-deactivated (only core-active) core-shell-type MOF catalysts was synthesized, which contain TEMPO groups on the ligand as active sites for aerobic oxidation of alcs. to afford aldehydes or ketones. The porous but catalytically inactive shell ensured the size-selective permeability by sieving effects and induced all reactions to took place in the pores of the catalytically active core. Because PSE is a facile and universal approach, this could be rapidly applied to a variety of MOF-based catalysts for enhancing reaction selectivity. In the experiment, the researchers used (4-Bromophenyl)methanol(cas: 873-75-6HPLC of Formula: 873-75-6)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.HPLC of Formula: 873-75-6 It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts