Hashimoto, Yuka; Hosokawa, Sasuga; Liang, Fengying; Suzuki, Yuto; Dai, Namin; Tana, Gegen; Eda, Kazuo; Kakiuchi, Toshifumi; Okazoe, Takashi; Harada, Hidefumi; Tsuda, Akihiko published an article in Journal of Organic Chemistry. The title of the article was 《Photo-on-Demand Base-Catalyzed Phosgenation Reactions with Chloroform: Synthesis of Arylcarbonate and Halocarbonate Esters》.Recommanded Product: 3,3,3-Trifluoropropan-1-ol The author mentioned the following in the article:
Carbonate esters are utilized as solvents and reagents for C1 building blocks in organic synthesis. This study reports a novel photo-on-demand in situ synthesis of carbonate esters with CHCl3 solutions containing a mixture of an aromatic or haloalkyl alc. having relatively high acidity, and an organic base. We found that the acid-base interaction of the alc. and base in the CHCl3 solution plays a key role in enabling the photochem. reaction. This reaction allows practical syntheses of di-Ph carbonate derivatives, haloalkyl carbonates, and polycarbonates, which are important chems. and materials in industry. After reading the article, we found that the author used 3,3,3-Trifluoropropan-1-ol(cas: 2240-88-2Recommanded Product: 3,3,3-Trifluoropropan-1-ol)
3,3,3-Trifluoropropan-1-ol(cas: 2240-88-2) is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.Recommanded Product: 3,3,3-Trifluoropropan-1-ol
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