Dong, Yi; Du, Nana; Li, Xueyuan; Zheng, Litao; Liu, Gang published the artcile< Tandem Chloropalladation/Cyclization and Dearomative Cyclization toward Functionalized Tricyclic Bridged [3.2.1] Skeleton Compounds>, SDS of cas: 4396-13-8, the main research area is fused tricyclic dienone chemoselective preparation; palladium copper catalyst aerobic dearomative cyclization alkenylphenylalkynyl carbonyl compound; tandem aerobic chloropalladation dearomative cyclization alkenylphenylalkynyl carbonyl compound; oxatricyclododecanecarboxamide mol crystal structure.
In the presence of PdCl2(MeCN)2 and CuCl2, o-alkenylphenylalkynyl carbonyl compounds such as allyloxyphenylpropynamide I underwent aerobic chemoselective dearomative cyclization reactions to yield fused tricyclic dienones such as II (R = MeO, BuO, EtO, PhCH2O, Me). The structure of II (R = PhCH2O) was determined by X-ray crystallog.
Organic Letters published new progress about Bicyclic compounds, ketones Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (bridged). 4396-13-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H6O5, SDS of cas: 4396-13-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts