Craven, Gregory B.; Briggs, Edward L.; Zammit, Charlotte M.; McDermott, Alexander; Greed, Stephanie; Affron, Dominic P.; Leinfellner, Charlotte; Cudmore, Hannah R.; Tweedy, Ruth R.; Luisi, Renzo; Bull, James A.; Armstrong, Alan published the artcile< Synthesis and Configurational Assignment of Vinyl Sulfoximines and Sulfonimidamides>, HPLC of Formula: 699-12-7, the main research area is vinyl sulfoximine preparation configurational assignment electronic CD; sulfonimidamide vinyl preparation configurational assignment electronic CD.
Herein, a range of different synthetic methodologies for constructing vinyl sulfoximine and vinyl sulfonimidamide architectures that allowed access to new areas of electrophilic chem. space was reported. Here how late-stage functionalization could be applied to these motifs to incorporate alkyne tags, generating fully functionalized probes for future chem. biol. applications was also demonstrated. Finally, a workflow for determining the absolute configuration of enantioenriched vinyl sulfoximines and sulfonimidamides was established by comparing exptl. and computationally determined electronic CD spectra, enabling access to configurationally assigned enantiomeric pairs by separation
Journal of Organic Chemistry published new progress about Absolute configuration. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, HPLC of Formula: 699-12-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts