Bunno, Youka; Tsukimawashi, Yuta; Kojima, Masahiro; Yoshino, Tatsuhiko; Matsunaga, Shigeki published the artcile< Metal-Containing Schiff Base/Sulfoxide Ligands for Pd(II)-Catalyzed Asymmetric Allylic C-H Aminations>, Computed Properties of 627-27-0, the main research area is chiral Schiff base sulfoxide ligand preparation; alkenyl oxazolidinone enantioselective preparation; asym allylic CH amination palladium catalyst Schiff base sulfoxide.
Metal-containing Schiff base/sulfoxides was developed as chiral ligands e.g., I, for Pd(II)-catalyzed asym. intramol. allylic C-H amination reactions. The use of metal-containing Schiff base ligands allowed tuning the selectivity and reactivity of Pd(II)-catalyst, whereby a Schiff base-Cu(II)/sulfoxide ligand in combination with Pd(OAc)2 showed best performance. Both internal and terminal alkenes were applicable and the C-H amination products were obtained in up to 91:9 er.
ACS Catalysis published new progress about Allylic amination. 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, Computed Properties of 627-27-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts