Product Details of 24388-23-6In 2020 ,《Rh-Catalyzed Base-Free Decarbonylative Borylation of Twisted Amides》 appeared in Journal of Organic Chemistry. The author of the article were Bie, Fusheng; Liu, Xuejing; Shi, Yijun; Cao, Han; Han, Ying; Szostak, Michal; Liu, Chengwei. The article conveys some information:
We report the rhodium-catalyzed base-free decarbonylative borylation of twisted amides. The synthesis of versatile arylboronate esters from aryl twisted amides is achieved via decarbonylative rhodium(I) catalysis and highly selective N-C(O) insertion. The method is notable for a very practical, additive-free Rh(I) catalyst system. The method shows broad functional group tolerance and excellent substrate scope, including site-selective decarbonylative borylation/Heck cross-coupling via divergent N-C/C-Br cleavage and late-stage pharmaceutical borylation. The experimental process involved the reaction of 4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6Product Details of 24388-23-6)
4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6) also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaura reaction.Product Details of 24388-23-6
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