You, Peiye; Wei, Rongjia; Ning, Guohong; Li, Dan published the artcile< An Eosin Y Encapsulated Cu(I) Covalent Metal Organic Framework For Efficient Photocatalytic Sonogashira Cross-Coupling Reaction>, HPLC of Formula: 10602-04-7, the main research area is Eosin Y encapsulated copper covalent metal organic framework preparation; internal alkyne selective preparation; iodobenzene alkyne Sonogashira cross coupling copper photocatalyst.
Herein, the encapsulation of an organic dye(i.e., Eosin Y, EY) into a Cu(I) cyclic trinuclear unit(CTU) based covalent-metal organic framework(CMOF), namely EY@JNM-1, as photocatalyst for the Sonogashira cross-coupling reaction of iodobenzene with alkynes to afford internal alkynes I [R = Ph, 4-MeC6H4, 4-ClC6H4, etc.] was reported. The EY@JNM-1 not only exhibited high catalytic activity for the alkynes(>99% conversion) and excellent selectivity for the cross-coupling product(>99%) under mild conditions, but also displayed excellent stability and recyclability.
Chemical Research in Chinese Universities published new progress about Alkynes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 10602-04-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C9H8O, HPLC of Formula: 10602-04-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts