《Synthesis of 1,3-Bis-(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2-Migration》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to You, Cai; Studer, Armido. HPLC of Formula: 78782-17-9 The article mentions the following:
A general and efficient approach for the preparation of 1,3-bis(boryl)alkanes is introduced. It is shown that readily generated vinylboron ate complexes react with com. available ICH2Bpin to valuable 1,3-bis-(boryl)alkanes. The introduced transformation, which is exptl. easy to conduct, shows broad substrate scope and high functional-group tolerance. Mechanistic studies reveal that the reaction does not proceed via radical intermediates. Instead, an unprecedented boronic ester induced sequential bis-1,2-migration cascade is suggested. The results came from multiple reactions, including the reaction of Bis[(pinacolato)boryl]methane(cas: 78782-17-9HPLC of Formula: 78782-17-9)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds are versatile intermediates and as such are some of the most important classes of reagents in modern organic chemistry. This stems from their ease of preparation combined with their ability to undergo a broad range of chemical transformations.HPLC of Formula: 78782-17-9
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