Wollenburg, Marco; Moock, Daniel; Glorius, Frank published the artcile< Hydrogenation of Borylated Arenes>, Recommanded Product: 2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine, the main research area is hydrogenation stereoselective borylated arene rhodium catalyst; crystal structure mol boronic acid ester preparation; arene hydrogenation; boronic esters; cycloalkanes; heterocycles; synthetic building blocks.
A cis-selective hydrogenation of abundant aryl boronic acids and their derivatives catalyzed by rhodium cyclic (alkyl)(amino)carbene (Rh-CAAC) is reported. The reaction tolerates a variety of boron-protecting groups and provides direct access to a broad scope of saturated, borylated carbo- and heterocycles with various functional groups. The transformation is strategically important because the versatile saturated boronate products are difficult to prepare by other methods. The utility of the saturated cyclic building blocks was demonstrated by post-functionalization of the boron group.
Angewandte Chemie, International Edition published new progress about Aromatic hydrocarbons Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (borylated). 660867-80-1 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H18BNO2, Recommanded Product: 2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine.
Referemce:
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Alcohols – Chemistry LibreTexts