Wang, Rongzhou; Qi, Jipeng; Yue, Yuancheng; Lian, Zhe; Xiao, Haibin; Zhuo, Shuping; Xing, Lingbao published the artcile< Ambient-pressure hydrogenation of ketones and aldehydes by a metal-ligand bifunctional catalyst [Cp*Ir(2,2'-bpyO)(H2O)] without using base>, Quality Control of 403-41-8, the main research area is secondary alc preparation green chem; ketone hydrogenation bifunctional iridium complex catalyst; primary alc preparation green chem; aldehyde hydrogenation bifunctional iridium complex catalyst.
An efficient catalytic system for hydrogenation of ketones R1C(O)R2 [R1 = Me, 3,4-dichlorophenyl, 2-naphthyl, pyridin-2-yl, etc.; R2 = Me, Pr, hexyl; R1R2 = -(CH2)5-] and aldehydes R3CHO (R3 = nonyl, cyclohexyl, 4-cyanophenyl, pyridin-2-yl, etc.) using a Cp*Ir complex [Cp*Ir(2,2′-bpyO)(H2O)] bearing a bipyridine-based functional ligand as catalyst has been developed. A wide variety of secondary and primary alcs. (R1)(R2)CHOH and R3CH2OH resp. was synthesized by the catalyzed hydrogenation of ketones and aldehydes under facile atm.-pressure without a base. The catalyst also displays an excellent chemoselectivity towards other carbonyl functionalities and unsaturated motifs. This catalytic system exhibits high activity for hydrogenation of ketones and aldehydes with H2 gas.
Tetrahedron published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Quality Control of 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts