In 2022,Mansour, Ritam; Mukherjee, Saikat; Pinheiro, Max Jr.; Noble, Jennifer A.; Jouvet, Christophe; Barbatti, Mario published an article in Physical Chemistry Chemical Physics. The title of the article was 《Pre-Dewar structure modulates protonated azaindole photodynamics》.Application In Synthesis of Oxetan-3-ol The author mentioned the following in the article:
Recent exptl. work revealed that the lifetime of the S3 state of protonated 7-azaindole is about ten times longer than that of protonated 6-azaindole. We simulated the nonradiative decay pathways of these mols. using trajectory surface hopping dynamics after photoexcitation into S3 to elucidate the reason for this difference. Both isomers mainly follow a common ππ* relaxation pathway involving multiple state crossings while coming down from S3 to S1 in the subpicosecond time scale. However, the simulations reveal that the excited-state topogs. are such that while the 6-isomer can easily access the region of nonadiabatic transitions, the internal conversion of the 7-isomer is delayed by a pre-Dewar bond formation with a boat conformation.Oxetan-3-ol(cas: 7748-36-9Application In Synthesis of Oxetan-3-ol) was used in this study.
Oxetan-3-ol(cas: 7748-36-9) is used as a reagent in the synthesis of 5-fluoro-4,6-dialkoxypyrimidine GPR119 agonists. It is also used as a reagent in the synthesis of cyclic sulfone hydroxyethylamines as potent and selective β-site APP-cleaving enzyme 1 (BACE1) inhibitors.Application In Synthesis of Oxetan-3-ol
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