Magre, Marc; Paffenholz, Eva; Maity, Bholanath; Cavallo, Luigi; Rueping, Magnus published the artcile< Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C-O Bond Activation>, Quality Control of 403-41-8, the main research area is secondary tertiary alc regiodivergent synthesis hydroborative ring opening epoxide.
A magnesium-catalyzed regiodivergent C-O bond cleavage protocol is presented. Readily available magnesium catalysts achieve the selective hydroboration of a wide range of epoxides and oxetanes yielding secondary and tertiary alcs. in excellent yields and regioselectivities. Exptl. mechanistic investigations and DFT calculations provide insight into the unexpected regiodivergence and explain the different mechanisms of the C-O bond activation and product formation.
Journal of the American Chemical Society published new progress about C-O bond activation. 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Quality Control of 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts