Ma, Shuai; Cui, Jing-Wang; Rao, Cai-Hui; Jia, Meng-Ze; Chen, Yun-Rui; Zhang, Jie published the artcile< Boosting activity of molecular oxygen by pyridinium-based photocatalysts for metal-free alcohol oxidation>, HPLC of Formula: 403-41-8, the main research area is boosting oxygen pyridinium photocatalyst metal alc oxidation.
An eco-friendly and economical approach for the photocatalytic oxidation of organic inter-mediates by air under mild conditions is highly desirable in green and sustainable chem., where the photogeneration of active oxygen species plays a key role in improving conversion efficiency and selectivity. By using pyridinium derivatives as mol. mediators for electron transfer and energy transfer, the simultaneous activation of O2 from air into superoxide radicals and singlet oxygen species can be achieved, and a photoinduced electron transfer catalytic system for the oxidation of alcs. has been developed. Thus, we have successfully simplified the complicated catalytic system into a single mol. catalyst without any addnl. noble metals and co-catalysts/additives. The current photocatalytic system shows high catalytic efficiency not only for aromatic alcs. but also for aliphatic alcs. that are generally difficult to undergo aerobic oxidation at room temperature under air atm., representing an ideal photocatalytic platform for green and economical organic syntheses.
Green Chemistry published new progress about Crystal structure. 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, HPLC of Formula: 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts