In 2017,Liu, Xun; Deaton, T. Maxwell; Haeffner, Fredrik; Morken, James P. published 《A Boron Alkylidene-Alkene Cycloaddition Reaction: Application to the Synthesis of Aphanamal》.Angewandte Chemie, International Edition published the findings.Application In Synthesis of Bis[(pinacolato)boryl]methane The information in the text is summarized as follows:
The authors describe an unusual net [2+2] cycloaddition reaction between B alkylidenes and unactivated alkenes. This reaction provides a new method for the construction of carbocyclic ring systems bearing versatile organoboronic esters. Aside from surveying the scope of this reaction, the authors provide details about the mechanistic underpinnings of this process, and examine its application to the synthesis of the natural product aphanamal. In the experiment, the researchers used Bis[(pinacolato)boryl]methane(cas: 78782-17-9Application In Synthesis of Bis[(pinacolato)boryl]methane)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds are versatile intermediates and as such are some of the most important classes of reagents in modern organic chemistry. This stems from their ease of preparation combined with their ability to undergo a broad range of chemical transformations.Application In Synthesis of Bis[(pinacolato)boryl]methane
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