Li, Hai-Lou; Lian, Chen; Yang, Guo-Yu published the artcile< A {Ti6W4}-Cluster-Substituted Polyoxotungstate: Synthesis, Structure, and Catalytic Oxidation Properties>, Recommanded Product: 2-(Phenylthio)ethanol, the main research area is methylammonium titanium tungstoantimonate cluster preparation crystal mol structure catalyst; oxidation catalyst methylammonium titanium tungstoantimonate cluster preparation.
A novel Ti-W-oxo-cluster substituted tungstoantimonate (TA) [H2N(CH3)2]3Na4H9[{Ti6W4O18(OH)(H2O)3}(B-α-SbW9O33)3]•20H2O (1) has been made by hydrothermal reactions of trivacant [B-α-SbW9O33]9- units, Ti4+ cations and WO42- anions in the presence of [H2N(CH3)2]•Cl and structurally characterized. Intriguingly, the polyoxoanion of 1 is constructed from three [B-α-SbW9O33]9- units and a previously unobserved decanuclear heterometallic Ti-W-oxo-cluster [Ti6W4O18(OH)(H2O)3]11+ {Ti6W4} that is comprised of an octahedral [Ti6WO6(H2O)3]18+ cluster and an edge-sharing [W3O12(OH)]7- fragment via six W-O-Ti/W linkers. Furthermore, studies on the catalytic oxidation properties reveal that 1 possesses good catalytic activity toward the oxidation reactions of various sulfides and cyclooctene basing on the environmentally friendly oxidant H2O2.
Inorganic Chemistry published new progress about Crystal structure. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Recommanded Product: 2-(Phenylthio)ethanol.
Referemce:
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