《Boron-Promoted Ether Interchange Reaction: Synthesis of Alkyl Nitroaromatic Ethers from Methoxynitroarenes》 was written by Liu, Zhenwei; Luan, Nannan; Lu, Hongtao; Liang, Apeng; Li, Jingya; Zou, Dapeng; Wu, Yangjie; Wu, Yusheng. SDS of cas: 78782-17-9 And the article was included in European Journal of Organic Chemistry in 2020. The article conveys some information:
In the presence of either bis(pinacolatoboryl)methane or Ph pinacolboronate, aryl ethers such as 2-nitroanisole underwent ether exchange reactions with alcs. ROH (R = t-Bu, EtCMe2, i-Pr, s-Bu, i-Bu, n-Pr, Bu, BuCH2, H2C:CHCH2, H2C:CMeCH2, cyclopropylmethyl, 2-tetrahydrofurfuryl, 4-tetrahydropyranmethyl, MeOCH2CH2OCH2CH2, H2C:CHCH2OCH2CH2) mediated by KOt-Bu at 90° to yield nitroaryl ethers such as 2-O2NC6H4OR (R = t-Bu, EtCMe2, i-Pr, s-Bu, i-Bu, n-Pr, Bu, BuCH2, H2C:CHCH2, H2C:CMeCH2, cyclopropylmethyl, 2-tetrahydrofurfuryl, 4-tetrahydropyranmethyl, MeOCH2CH2OCH2CH2, H2C:CHCH2OCH2CH2). In the experiment, the researchers used Bis[(pinacolato)boryl]methane(cas: 78782-17-9SDS of cas: 78782-17-9)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.SDS of cas: 78782-17-9
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