Al-Masri, Harbi Tomah; Almejled, Akram Ali published the artcile< Hg(II) and Ru(II) complexes of mono- and dichalcogenides of bis(diphenylphosphino)amine chelating ligands: Synthesis, characterization and catalytic activity in transfer hydrogenation of acetophenone derivatives>, Application In Synthesis of 403-41-8, the main research area is ruthenium aminobisphosphino iodo carbonyl complex catalyst preparation crystal structure; transfer hydrogenatio catalyst ruthenium aminobisphosphino iodo carbonyl complex.
Reactions of C10H7-1-N(PPh2)2 (1) and C10H7-1-N(P(Se)Ph2)2 (2) ligands with mercury(II)iodide in equimolar ratio gave cis-[HgI2{-κ2P,P}] (3) and cis-[HgI2{-κ2Se,Se}] (4). Also, refluxing of monooxidized thioyl and selenoyl bis(phosphino)amine ligands C10H7-1-N(P(E)Ph2)(PPh2) (E = S (5), Se (6)) with [Ru(CO)3Cl2]2 dimer afforded cis-[Ru(CO)2Cl2{-κ2P,S}] (7) and cis-[Ru(CO)2Cl2{-κ2P,Se}] (8). Complexes , , and were identified and characterized by multinuclear NMR (1H, 13C, 31P and 77Se NMR) and IR spectroscopy. The mol. structure of was determined by single x-ray crystallog. is the first structurally characterized example of this kind of κ2P,S -bidentate ligand. The novel ruthenium(II) complexes and show high catalytic activity in the transfer hydrogenation of acetophenone derivatives to 1-phenylethanol derivatives in the presence of 2-propanol as the hydrogen source.
Phosphorus, Sulfur and Silicon and the Related Elements published new progress about Chalcogenides Role: RCT (Reactant), RACT (Reactant or Reagent) (di-). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Application In Synthesis of 403-41-8.
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