Yadav, Vishal; Gordon, Jesse B.; Siegler, Maxime A.; Goldberg, David P. published the artcile< Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals>, Formula: C19H16O, the main research area is neopentylamine dioxygen nonheme mononuclear iron hydroxide preparation reactivity carbon; carbon radical reactivity neopentylamine dioxygen nonheme mononuclear iron hydroxide; crystal mol structure neopentylamine dioxygen nonheme mononuclear iron hydroxide.
A new tetradentate, monoanionic, mixed N/O donor ligand (BNPAPh2O-) with second coordination sphere H-bonding groups has been synthesized for stabilization of a terminal FeIII(OH) complex. The complex FeII(BNPAPh2O)(OTf) (1) reacts with O2 to give a mononuclear terminal FeIII(OH) complex, FeIII(OH)(BNPAPh2O)(OTf) (2), both of which were characterized by x-ray diffraction, electrospray ionization mass spectrometry, UV-vis, 1H and 19F NMR, 57Fe Moessbauer, and ESR spectroscopies. Treatment of 2 with carbon radicals (Ar3C·) gives Ar3COH and the FeII complex 1, in direct analogy with the elusive radical “”rebound”” process proposed for nonheme iron enzymes.
Journal of the American Chemical Society published new progress about Coordination sphere. 76-84-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C19H16O, Formula: C19H16O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts