Tressl, Roland; Kersten, Evelyn; Wondrak, Georg; Rewicki, Dieter; Kruger, Ralph-Peter published the artcile< Fragmentation of sugar skeletons and formation of Maillard polymers>, Formula: C6H9NO, the main research area is fragmentation pathway sugar skeleton; Maillard polymer formation.
Labeling experiments involving the reaction of 13C-labeled hexoses, pentoses, and D-lactose with 4-aminobutyric acid (GABA) (isoleucine) are described. The distribution of the label was investigated by MS and gave an insight into the formation pathways leading to complementary labeled compounds from hexoses and pentoses with intact carbon skeletons and indicated distinct fragmentations of the sugar skeletons into C5- and C4-compounds (furans, N-alkylpyrrolemethanols, N-alkyl-2-formylpyrroles and N-alkylpyrroles). These compounds undergo polycondensations to melanoidin-like macromols. under mild reaction conditions. In a series of model experiments, different types of polymers were investigated, and individual oligomers (e.g. I) were characterized by 1H/13C-NMR spectroscopy and FAB-/MALDI-TOF-MS. The authors postulate that these polycondensation reactions represent the most important driving force in the Maillard reaction.
Special Publication – Royal Society of Chemistry published new progress about Fragmentation reaction. 52160-51-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C6H9NO, Formula: C6H9NO.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts