Tang, Yun-Zhi; Tan, Yu-Hui; Ge, Zong-Tang; Liu, Zhen-Xin; Liao, Chun-Fa; Xie, Xiao-Bin published the artcile< Synthesis and crystal structures of two rare-earth metal polymers of olsalazine>, Safety of Sodium 5,5′-(diazene-1,2-diyl)bis(2-hydroxybenzoate), the main research area is rare earth olsalazine phenanthroline polymer complex preparation structure; europium gadolinium olsalazine phenanthroline polymer complex preparation structure; crystal structure europium gadolinium olsalazine phenanthroline polymer complex.
Two 1-dimensional linear coordination polymers, {[Gd2(L)2·(Phen)2·2(H2O)·2(NO3)]·2(EtOH)}n (1, H2L = olsalazine) and {[Eu2(L)2·(Phen)2·2(H2O)·2(NO3)]·EtOH}n (2), were obtained from self-assembly of Gd(NO3)3·8H2O or Eu(NO3)3·8H2O with olsalazine. Both complexes are 1-dimensional polymers, for 1 with crystal data: space group P1̅, a 11.651(4), b 11.865(4), and c 12.296(4) Å, α 77.984(4), β 65.559(4), and γ 74.558(5)°, Z = 1, R1 = 0.0389, wR2 = 0.0793, and 2 with crystal data: space group P1̅, a 11.626(3), b 11.834(3), c 12.287(4) Å, α 77.743(3), β 65.576(3), γ 74.371(3)°, Z = 1, R1 = 0.0609, wR2 = 0.1185. Central atoms (Gd or Eu) in both complexes adopt nine-coordinate tricapped trigonal prismatic geometry.
Journal of Coordination Chemistry published new progress about Crystal structure. 6054-98-4 belongs to class alcohols-buliding-blocks, and the molecular formula is C14H8N2Na2O6, Safety of Sodium 5,5′-(diazene-1,2-diyl)bis(2-hydroxybenzoate).
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