Sau, Abhijit; Palo-Nieto, Carlos; Galan, M. Carmen published the artcile< Substrate-Controlled Direct α-Stereoselective Synthesis of Deoxyglycosides from Glycals Using B(C6F5)3 as Catalyst>, Related Products of 4064-06-6, the main research area is stereoselective glycosylation catalyst boron glycal disaccharide.
B(C6F5)3 enables the metal-free unprecedented substrate-controlled directαstereoselective synthesis of deoxyglycosides from glycals. 2,3-UnsaturatedαO-glycoside products are obtained with deactivated glycals at 75 degrees C in the presence of the catalyst, while 2-deoxyglycosides are formed using activated glycals that bear no leaving group at C-3 at lower temperatures The reaction proceeds in good to excellent yields via concomitant borane activation of glycal donor and nucleophile acceptor. The method is exemplified with the synthesis of a series of rare and biol. relevant oligosaccharide analogs.
Journal of Organic Chemistry published new progress about 4064-06-6. 4064-06-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H20O6, Related Products of 4064-06-6.
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