Safety of Bis[(pinacolato)boryl]methaneIn 2018 ,《Enantioselective Construction of Tertiary Boronic Esters by Conjunctive Cross-Coupling》 was published in Angewandte Chemie, International Edition. The article was written by Myhill, Jesse A.; Zhang, Liang; Lovinger, Gabriel J.; Morken, James P.. The article contains the following contents:
Catalytic enantioselective conjunctive cross-coupling has been developed to construct tertiary alkylboronic esters. These reactions occur with good yield and enantioselectivity for a range of substrates. Mechanistic experiments reveal aspects of the catalytic cycle that allow hindered substrates to react without significant complicating side reactions. After reading the article, we found that the author used Bis[(pinacolato)boryl]methane(cas: 78782-17-9Safety of Bis[(pinacolato)boryl]methane)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Safety of Bis[(pinacolato)boryl]methane Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.
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