Category: alcohols-buliding-blocksIn 2017 ,《Copper-catalyzed propargylation of diborylmethane》 appeared in Chemical Communications (Cambridge, United Kingdom). The author of the article were Li, Feng; Zhang, Zhen-Qi; Lu, Xi; Xiao, Bin; Fu, Yao. The article conveys some information:
A Cu/PPh3-catalyzed propargylic substitution reaction of diborylmethane is reported. Different substituted propargyl electrophiles can be employed in this reaction, and various synthetic valuable functional groups can be tolerated. Di-deuterated diborylmethane can also be used under these conditions and generates α-deuterated alkylboronic esters in good yield. In the experiment, the researchers used Bis[(pinacolato)boryl]methane(cas: 78782-17-9Category: alcohols-buliding-blocks)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Category: alcohols-buliding-blocks Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.
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