《Iron(II)-Catalyzed Biomimetic Aerobic Oxidation of Alcohols》 was published in Angewandte Chemie, International Edition in 2020. These research results belong to Guethmundsson, Arnar; Schlipkoeter, Kim Elisabeth; Baeckvall, Jan-E.. COA of Formula: C7H7BrO The article mentions the following:
The first iron(II)-catalyzed biomimetic aerobic oxidation of alcs was reported. The principle of this oxidation, which involved several electron-transfer steps, was reminiscent of biol. oxidation in respiratory chain. The electron transfer from alc. to mol. oxygen occurred with aid of three coupled catalytic redox systems, led to a low-energy pathway. An iron transfer-hydrogenation complex was utilized as a substrate-selective dehydrogenation catalyst, along with an electron-rich quinone and an oxygen-activating Co(salen)-type complex as electron-transfer mediators. Various primary and secondary alcs. were oxidized in air to the corresponding aldehydes or ketones with this method in good to excellent yields. In the part of experimental materials, we found many familiar compounds, such as (4-Bromophenyl)methanol(cas: 873-75-6COA of Formula: C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.COA of Formula: C7H7BrO It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts