《Diastereo- and Enantioselective Synthesis of Homoallylic Amines Bearing Quaternary Carbon Centers》 was published in Journal of the American Chemical Society in 2020. These research results belong to Green, Jacob C.; Zanghi, Joseph M.; Meek, Simon J.. Synthetic Route of C13H26B2O4 The article mentions the following:
A Cu-catalyzed method for the efficient enantio- and diastereoselective synthesis of chiral homoallylic amines bearing a quaternary C and an alkenylboron is disclosed. Transformations are promoted by a readily prepared (phosphoramidite)-Cu complex and involve bench-stable γ,γ-disubstituted allyldiborons and benzyl imines; products were obtained in up to 82% yield, >20:1 dr, and >99:1 er. Reactions proceed via stereodefined B-stabilized allylic Cu species formed by an enantioselective transmetalation. Utility of the 1-amino-3-alkenylboronate products is highlighted by a variety of synthetic transformations. In addition to this study using Bis[(pinacolato)boryl]methane, there are many other studies that have used Bis[(pinacolato)boryl]methane(cas: 78782-17-9Synthetic Route of C13H26B2O4) was used in this study.
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Synthetic Route of C13H26B2O4 Organoboron compounds are versatile intermediates and as such are some of the most important classes of reagents in modern organic chemistry. This stems from their ease of preparation combined with their ability to undergo a broad range of chemical transformations.
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