In 2017,Edelstein, Emma K.; Namirembe, Sheila; Morken, James P. published 《Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents》.Journal of the American Chemical Society published the findings.Product Details of 78782-17-9 The information in the text is summarized as follows:
Pd-catalyzed conjunctive cross-coupling was used for the synthesis of enantioenriched allylboron reagents. This reaction employs nonsym. bis(alkenyl)borates as substrates and appears to occur by a mechanism that involves selective activation of the less substituted alkene followed by migration of the more substituted alkene during a Pd-induced metalate rearrangement.Bis[(pinacolato)boryl]methane(cas: 78782-17-9Product Details of 78782-17-9) was used in this study.
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds.Product Details of 78782-17-9 Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.
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