Zu, Yujia; Cai, Chenglin; Sheng, Jingyuan; Cheng, Lili; Feng, Yingle; Zhang, Shengyong; Zhang, Qi; Chai, Yonghai published the artcile< n-Pentenyl-Type Glycosides for Catalytic Glycosylation and Their Application in Single-Catalyst One-Pot Oligosaccharide Assemblies>, Synthetic Route of 4064-06-6, the main research area is pentenyl glycoside catalytic stereoselective glycosylation oligosaccharide preparation.
We have developed a new type of n-pentenyl-type glycosides that can be activated by catalytic amounts of promoter, Hg(NTf2)2 or PPh3AuCl/AgNTf2, at room temperature The mild activation conditions and outstanding stability of common protection/deprotection manipulations enable the enynyl donors to have broad applications in constructing various glycosidic bonds. Furthermore, under the Hg(NTf2)2-catalyzed conditions, the sequential activation of different types of donors was achieved, based on which a gentio-tetrasaccharide was synthesized via the newly developed single-catalyst one-pot strategy.
Organic Letters published new progress about Glycosides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 4064-06-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H20O6, Synthetic Route of 4064-06-6.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts