Zhong, Mingbing; Gagne, Yohann; Hope, Taylor O.; Pannecoucke, Xavier; Frenette, Mathieu; Jubault, Philippe; Poisson, Thomas published the artcile< Copper-Photocatalyzed Hydroboration of Alkynes and Alkenes>, Computed Properties of 10602-04-7, the main research area is copper photocatalyst diphosphinoxanthene diphosphinophenoxazine phenanthroline complex preparation electrochem absorbance; hydroboration alkyne alkene copper photocatalyst preparation stereoselective regioselective mechanism; mol structure optimized boronic ester free energy enthalpy dissociation; boryl radical; continuous flow; copper; hydroboration; photocatalysis.
The photocatalytic hydroboration of alkenes and alkynes is reported. The use of newly-designed copper photocatalysts with B2Pin2 permits the formation a boryl radical, which is used for hydroboration of a large panel of alkenes and alkynes. The hydroborated products were isolated in high yields, with excellent diastereoselectivities and a high functional group tolerance under mild conditions. The hydroboration reactions were developed under continuous flow conditions to demonstrate their synthetic utility. The reaction mechanism was studied and suggested an oxidation reaction between an in situ formed borate and the Cu-photocatalyst in its excited state for the boryl radical formation.
Angewandte Chemie, International Edition published new progress about Activation enthalpy. 10602-04-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C9H8O, Computed Properties of 10602-04-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts