Skolia, Elpida; Gkizis, Petros L.; Nikitas, Nikolaos F.; Kokotos, Christoforos G. published the artcile< Photochemical aerobic oxidation of sulfides to sulfoxides: the crucial role of wavelength irradiation>, COA of Formula: C8H10OS, the main research area is sulfoxide green preparation; sulfide aerobic photochem oxidation.
Herein, a novel, sustainable, light-driven protocol was reported for photochem. aerobic oxidation of sulfides to sulfoxides RS(O)R1 [R = Ph, naphth-2-yl, n-Bu, etc.; R1 = Me, Et, n-Pr, etc.], where the impact of wavelength irradiation on sulfide aerobic photooxidation was examined In this work, two different low-catalyst loading (0.05-0.5 mol%) protocols, utilizing anthraquinone as the photocatalyst (under CFL lamps or 427 nm irradiation) were developed and a catalyst-free protocol (under 370 nm irradiation) was also assessed. In addition, a broad scope of substrates was tested and extensive mechanistic studies were performed, in order to distinguish the mechanistic pathways that were followed in the different cases of aryl or alkyl sulfide oxidation under different wavelength irradiation Also implemented this protocols toward the oxidation of several intermediates en route to Sulforaphane.
Green Chemistry published new progress about Bromoalkanes Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, COA of Formula: C8H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts