Sahoo, Rajata Kumar; Mahato, Mamata; Jana, Achintya; Nembenna, Sharanappa published the artcile< Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones>, SDS of cas: 403-41-8, the main research area is zinc guanidinate hydride catalyst hydrosilylation hydroboration ketone.
Three new dimeric bis-guanidinate zinc(II) alkyl, halide, and hydride complexes [LZnEt]2 (1), [LZnI]2 (2) and [LZnH]2 (3) (I – III, resp., R = 2,6-Et2C6H3 ) were prepared Compound 3 was successfully employed for the hydrosilylation and hydroboration of a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up to 5800 h-1, outperforming that of reported zinc hydride catalysts. Notably, both intra- and intermol. chemoselective hydrosilylation and hydroboration reactions have been investigated.
Journal of Organic Chemistry published new progress about Alkoxysilanes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, SDS of cas: 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts