In 2022,Sagadevan, Arunachalam; Ghosh, Atanu; Maity, Partha; Mohammed, Omar F.; Bakr, Osman M.; Rueping, Magnus published an article in Journal of the American Chemical Society. The title of the article was 《Visible-Light Copper Nanocluster Catalysis for the C-N Coupling of Aryl Chlorides at Room Temperature》.Recommanded Product: 7748-36-9 The author mentioned the following in the article:
A copper nanocluster-based catalyst, [Cu61(StBu)26S6Cl6H14] (Cu61NC) that enabled C-N bond-forming reactions of aryl chlorides under visible-light irradiation at room temperature A range of N-heterocyclic nucleophiles and electronically and sterically diversed aryl/hetero chlorides react in this new Cu61NC-catalyzed process to afford the C-N coupling products in good yields. Mechanistic studies indicated that a single-electron-transfer (SET) process between the photoexcited Cu61NC complex and aryl halide enabled the C-N-arylation reaction. In the experiment, the researchers used many compounds, for example, Oxetan-3-ol(cas: 7748-36-9Recommanded Product: 7748-36-9)
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