Qu, Peiyuan; Kuepfert, Michael; Jockusch, Steffen; Weck, Marcus published the artcile< Compartmentalized Nanoreactors for One-Pot Redox-Driven Transformations>, Product Details of C8H9FO, the main research area is micellar compartmentalized nanoreactor catalyst preparation redox deracemization secondary alc; polyoxazoline synthesis nanoreactor.
This contribution introduces poly(2-oxazoline)-based shell cross-linked micelles (SCMs) as nanoreactors to realize one-pot redox-driven deracemizations of secondary alcs. in aqueous media. TEMPO and Rh-TsDPEN moieties are spatially positioned into the hydrophilic corona and the hydrophobic micelle core, resp. TEMPO catalyzes the oxidation of racemic secondary alcs. into ketones, while Rh-TsDPEN catalyzes the asym. transfer hydrogenation (ATH) of these ketones to afford enantioenriched secondary alcs. Both catalysts, the Rh-TsDPEN complex and TEMPO, are incompatible with each other and the SCMs are designed to provide indispensable catalyst site isolation. Kinetic studies show that the SCMs enhance the reactivity of the immobilized catalysts, in comparison to those for the unsupported analogs under the same reaction conditions. Our nanoreactors can perform deracemizations on a broad range of secondary alc. substrates and are reusable in a continuous manner while maintaining high activity.
ACS Catalysis published new progress about ESR (electron spin resonance). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Product Details of C8H9FO.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts