P., Sreejyothi; Sarkar, Pallavi; Dutta, Supriti; Das, Arpan; Pati, Swapan K.; Mandal, Swadhin K. published the artcile< Regioselective ring-opening of epoxides towards Markovnikov alcohols: a metal-free catalytic approach using abnormal N-heterocyclic carbene>, Application In Synthesis of 403-41-8, the main research area is alkyl epoxide borabicyclononane heterocyclic carbene regioselective Markovnikov ring opening; alkanol preparation.
The first metal-free regioselective Markovnikov ring-opening of epoxides (selectivity up to 99%) using an abnormal N-heterocyclic carbene (aNHC) to yield secondary alcs was reported. DFT calculations and X-ray crystallog. suggested that the Markovnikov selectivity originated from the high nucleophilicity and steric factors associated with the aNHC.
Chemical Communications (Cambridge, United Kingdom) published new progress about Aliphatic alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Application In Synthesis of 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts