Nishiyama, Yutaka; Xu, Shijie; Hanatani, Yuuki; Tsuda, Susumu; Umeda, Rui published the artcile< Rhenium complex-catalyzed deoxygenation and silylation of alcohols with hydrosilane>, Reference of 76-84-6, the main research area is alc rhenium catalyst reduction; hydrocarbon preparation; hydrosilane alc rhenium catalyst silylation; silyl ether preparation.
The reduction of benzylic, tertiary, and allylic alcs. with hydrosilane was efficiently catalyzed by the rhenium complex, such as ReBr(CO)5, to give the corresponding deoxygenarated products, alkanes, in moderate to good yields. In the case of aliphatic secondary alc., the alkane was formed along with the formation of dehydrated products. On the other hand, in the case of primary and cyclic alcs., silylation of alcs. proceeded to form the corresponding silyl ethers.
Tetrahedron Letters published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 76-84-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C19H16O, Reference of 76-84-6.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts