Mou, Xue-Qing; Ren, Liang-Chen; Zhang, Mei; Wang, Min; Jin, Yu-Fan; Guan, Qing-Xin; Cai, Ang; Zhang, Shi-Min; Ren, Hai; Zhang, Yun; Chen, Yong-Zheng published the artcile< Complementary Copper-Catalyzed and Electrochemical Aminosulfonylation of O-Homoallyl Benzimidates and N-Alkenyl Amidines with Sodium Sulfinates>, HPLC of Formula: 627-27-0, the main research area is alkylsulfonyl oxazine preparation; benzimidate sodium sulfinate copper catalyst aminosulfonylation; alkyl sulfonyl tetrahydropyrimidine preparation; alkenyl amidine sodium sulfinate copper catalyst aminosulfonylation; sulfonyl oxazepine preparation; sodium sulfinate benzimidate trichloroacetimidate copper electrochem aminosulfonylation cyclization regioselective.
A complementary copper-catalyzed and electrochem. aminosulfonylation of O-homoallyl benzimidates/N-alkenyl amidines with sodium sulfinates were developed. The terminal alkene substrate produced Sulfone-containing 1,3-oxazines and tetrahydropyrimidines in the presence of Cu(OAc)2, Ag2CO3 and DPP, and under similar reaction conditions, sulfonylated tetrahydro-1,3-oxazepines were prepared from 1-aryl-substituted O-homoallyl benzimidates in moderate to good yields. For certain electron-rich 1,1- diaryl-substituted alkene substrate, corresponding tetrahydro-1,3-oxazepines was also be obtained in similar or even higher yield via a green electrochem. technique.
Organic Letters published new progress about Alkenes Role: PRP (Properties), RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, HPLC of Formula: 627-27-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts