Medvedev, Alexander G.; Grishanov, Dmitry A.; Mikhaylov, Alexey A.; Churakov, Andrei V.; Tripol’skaya, Tatiana A.; Ottenbacher, Roman V.; Bryliakov, Konstantin P.; Shames, Alexander I.; Lev, Ovadia; Prikhodchenko, Petr V. published the artcile< Triphenyllead Hydroperoxide: A 1D Coordination Peroxo Polymer, Single-Crystal-to-Single-Crystal Disproportionation to a Superoxo/Hydroxo Complex, and Application in Catalysis>, Product Details of C19H16O, the main research area is lead organometallic peroxide superoxide preparation disproportionation structure; epoxidation reagent triphenyllead hydroperoxide preparation chiral epoxide; crystal structure lead organometallic peroxide superoxide hydroxide.
The synthesis, transformation, and application in catalysis of triphenyllead hydroperoxide, the first dioxygen lead complex, are described. Triphenyllead hydroperoxide is characterized by 207Pb NMR (NMR), Fourier transform IR spectroscopy (FTIR), Raman spectroscopy, and single-crystal X-ray diffraction, revealing the first one-dimensional (1D) coordination peroxo polymer. Photolytic isomorphous transformation of Ph3PbOOH yields a mixed hydroxo/superoxo crystalline structure, the first nonalkali superoxo crystalline metal salt, which is stable up to 100°C. Upon further photolysis, another isomorphous transformation of the superoxide to hydroxide is observed These are the first single-crystal-to-single-crystal hydroperoxide-to-superoxide and then to hydroxide transformations reported to date. Photolysis of triphenyllead hydroperoxide yields two forms of superoxide-doped crystalline structures that are distinguished by widely different characteristic relaxation times. The use of Ph3PbOOH as an easy-to-handle solid two-electron oxidant for the highly enantioselective epoxidation of olefins is described.
Inorganic Chemistry published new progress about Alkenes Role: RCT (Reactant), RACT (Reactant or Reagent). 76-84-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C19H16O, Product Details of C19H16O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts