Li, Hai-Lou; Lian, Chen; Yang, Guo-Yu published the artcile< {Ti6}/{Ti10} Wheel Cluster Substituted Silicotungstate Aggregates>, HPLC of Formula: 699-12-7, the main research area is titanium tungstosilicate wheel preparation thioether oxidation catalyst; crystal structure titanium tungstosilicate wheel cluster.
Two novel Ti-oxo wheel cluster substituted silicotungstates (STs) [H2NMe2]9H9[Ti6O6(SiW10O37)3]·11H2O (1) and [H2NMe2]16H10[Ti10O11(SiW10O37)2(SiW9O35)2]·14H2O (2) were made by hydrothermal reactions. The polyoxoanion of 1 is a ring-shaped trimer where a Ti6O6 ({Ti6}) wheel cluster is encapsulated by three divacant [SiW10O37]10- (SiW10O37) fragments. However, 2 is built by two divacant SiW10O37 units and two rare trivacant [SiW9O35]12- (SiW9O35) fragments and further installs an unprecedented Ti10O11 ({Ti10}) double-wheel cluster. To the best of the authors’ knowledge, 2 is rare in POM chem. Studies on the catalytic oxidation properties reveal that 1 exhibits high catalytic activity toward the oxidation of various sulfides using H2O2 as an oxidant. Also, 1 can be facilely recycled and reused for at least five cycles without obvious loss of catalytic activity.
Inorganic Chemistry published new progress about Cluster compounds Role: CAT (Catalyst Use), PRP (Properties), SPN (Synthetic Preparation), USES (Uses), PREP (Preparation). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, HPLC of Formula: 699-12-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts