Kucinski, Krzysztof; Stachowiak, Hanna; Hreczycho, Grzegorz published the artcile< Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes - an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes>, Safety of Triphenylmethanol, the main research area is silylation alc phenol silanol alkynylsilane green chem; silyl ether unsym siloxane preparation green chem.
The formation of several silyl ethers (alkoxysilanes, R3Si-OR’) and unsym. siloxanes (R3Si-O-SiR’3) can be catalyzed by the com. available potassium bis(trimethylsilyl)amide (KHMDS). The reaction proceeds via direct dealkynative coupling between various alcs. or silanols and alkynylsilanes, with a simultaneous formation of gaseous acetylene as the sole byproduct. The dehydrogenative and dealkenative coupling of alcs. or silanols are well-investigated, while the utilization of alkynylsilanes as silylating agents has never been comprehensively studied in this context. Overall, the presented system allows the synthesis of various attractive organosilicon compounds under mild conditions, making this approach an atom-efficient, environmentally benign, and sustainable alternative to existing synthetic solutions
European Journal of Organic Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 76-84-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C19H16O, Safety of Triphenylmethanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts