Kishore, Jugal; Thiyagarajan, Subramanian; Gunanathan, Chidambaram published the artcile< Ruthenium(II)-catalyzed direct synthesis of ketazines using secondary alcohols>, Recommanded Product: 1-(4-Fluorophenyl)ethyl Alcohol, the main research area is ketazine preparation diastereoselective; secondary alc hydrazine hydrate oxygen hydrogen bond activation; ruthenium pincer complex catalyst.
Direct one-pot synthesis of ketazines (E,E)-R1R2C:NN:CR1R2 (R1 = Me, Et, Pr, etc.; R2 = C6H5, 4-MeC6H4, 2-MeOC6H4, etc.) from secondary alcs. R1R2CH(OH) and hydrazine hydrate catalyzed by a ruthenium pincer complex is reported, which proceeds through O-H bond activation of secondary alcs. via amine-amide metal-ligand cooperation in the catalyst. Remarkably, liberated mol. hydrogen and water are the only byproducts.
Chemical Communications (Cambridge, United Kingdom) published new progress about Azines Role: SPN (Synthetic Preparation), PREP (Preparation) (ketazines). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, Recommanded Product: 1-(4-Fluorophenyl)ethyl Alcohol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts