Hwang, Chiwon’s team published research in Chemical Communications (Cambridge, United Kingdom) in 2017 | CAS: 78782-17-9

Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Recommanded Product: Bis[(pinacolato)boryl]methane

Recommanded Product: Bis[(pinacolato)boryl]methaneIn 2017 ,《Base-promoted, deborylative secondary alkylation of N-heteroaromatic N-oxides with internal gem-bis[(pinacolato)boryl]alkanes: a facile derivatization of 2,2′-bipyridyl analogues》 appeared in Chemical Communications (Cambridge, United Kingdom). The author of the article were Hwang, Chiwon; Jo, Woohyun; Cho, Seung Hwan. The article conveys some information:

A base-promoted, secondary alkylation of N-heteroaromatic N-oxides, e.g., I using internal gem-bis[(pinacolato)boryl]alkanes R1R2C(Bpin)2 [R1 = H, CH3, (CH2)5CH3; R2 = CH3, CH2C6H5, CH2HC=CH2, etc.] as alkylation reagents is reported. The reaction exhibits a broad scope, providing deoxygenated secondary alkylated N-heteroaromatic compounds, e.g., II with high efficiency. The usefulness of the developed protocol is evidenced by the sequential direct alkylation of 2,2′-bipyridine-N-oxide. In the experimental materials used by the author, we found Bis[(pinacolato)boryl]methane(cas: 78782-17-9Recommanded Product: Bis[(pinacolato)boryl]methane)

Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Recommanded Product: Bis[(pinacolato)boryl]methane

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